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Ognjen Š. Miljanić
Assistant Professor
Office: 35 Fleming
Phone: (713) 743-2718
Fax: (713) 743-2709
Email: miljanic@uh.edu

Education
Diploma University of Belgrade, Serbia, 2000
Ph.D. University of California, Berkeley, 2005
Postdoc University of California, Los Angeles 2005-2008

Honors and Fellowships
Postdoctoral Research Excellence Award (UCLA), 2008
Best Chemistry Student (University of Belgrade), 2000
Student of the Generation (University of Belgrade), 2000
Serbian Academy of Arts and Sciences Fellow, 1999–2000

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Research Interests
Synthetic and Supramolecular Chemistry

Nanospace Engineering through the Assembly of Nucleobases

Supramolecular interactions play a pivotal role in many biomolecules, often dictating both structure and function. The hydrogen bonding of nucleobases in DNA represents one of the most thoroughly understood naturally-occuring supramolecular motives. This ubiquitous building block will be used to construct unnatural discrete and extended (2D and 3D) superstructures through self-assembly. The former will be investigated as platforms for guest encapsulation and homogeneous catalysis; the latter, as materials for energy storage and chiral separations. Second generation of these materials will be endowed with switchable properties (polarity, pore size, chemical affinity).

Novel Metallocenic Scaffolds for Catalysis and Sensing

Previously unreported metallocenic scaffolds will be targeted, starting both from known and from yet undiscovered metallocene intermediates. These molecules will be used as (1) ligands for asymmetric catalysis; (2) precursors to heterogeneous size- and shape-selective catalysts, and (3) selective sensors for electron-rich small molecules.

The Miljanić lab relies on supramolecular and synthetic chemistry as its key tools. Synthesis is used in the broad sense of the word, encompassing organic, coordinative inorganic, and organometallic preparations. Spectroscopy, crystallography, and materials characterization are the most relevant analytical tools. Students and postdoctoral researchers in the Miljanić group receive detailed guidance in scientific writing and visualization. This diversified training is intended to prepare them for challenges in both academic and a variety of industrial work environments.


Recent Publications
Patel, K.; Miljanić, O. Š.; Stoddart, J. F. Iodide-Catalysed Self-Assembly of Donor-Acceptor [3]Catenanes, Chem. Commun. 2008, 1853–1855.

Miljanić, O. Š.; Stoddart, J. F. Dynamic Donor-Acceptor [2]Catenanes Proc. Natl. Acad. Sci. USA 2007, 104, 12966–12970.

Miljanić, O. Š.; Dichtel, W. R.; Khan, S. I.; Mortezaei, S.; Heath, J. R.; Stoddart, J. F. Structural and Co-Conformational Effects of Alkyne-Derived Subunits in Charged Donor-Acceptor [2]Catenanes J. Am. Chem. Soc. 2007, 129, 8236–8246.

Dichtel, W. R.; Miljanić, O. Š.; Spruell, J. M.; Heath, J. R.; Stoddart, J. F. Efficient Templated Synthesis of Donor-Acceptor Rotaxanes Using Click Chemistry J. Am. Chem. Soc. 2006, 128, 10388–10390.

Miljanić, O. Š.; Han, S.; Holmes, D.; Schaller, G. R.; Vollhardt, K. P. C. Hindered Rotation in an "Exploded" Biphenyl Chem. Commun. 2005, 2606–2608.

Kumaraswamy, S.; Jalisatgi, S. S.; Matzger, A. J.; Miljanić, O. Š.; Vollhardt, K. P. C. Anatomy of a Cyclohexatriene: Chemical Dissection of the s Frame of Angular [3]Phenylene Angew. Chem. Int. Ed. 2004, 43, 3711–3715.

Miljanić, O. Š.; Vollhardt, K. P. C.; Whitener, G. D. An Alkyne Metathesis-Based Route to ortho-Dehydrobenzannulenes Synlett 2003, 29–34.

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